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In collaboration with Tosoh Corporation, researchers in AIST developed a catalytic reaction for producing urea derivatives from low-concentration CO2 equivalent to thermal power plant exhaust gas. Urea derivatives are useful chemicals as raw materials for resins, solvents, and pharmaceuticals. In the NEDO project "NEDO Feasibility Study Program/Uncharted Territory Challenge 2050/Direct Conversion of Low-concentration CO2 Derived from Exhaust Gases into Useful Chemicals," R&D was performed on a synthesis process that directly converts low-concentration CO2 into useful chemicals such as polyurethane raw materials and led to development of this technology. This technology can efficiently synthesize various urea derivatives, such as the useful chemical ethylene urea, by acting a titanium catalyst on ammonium carbamate, which is easily obtained from amines and low-concentration CO2 (volume ratio 15 %) equivalent to the exhaust gas at coal-fired power plants. In addition, low-concentration CO2 in thermal power plant exhaust gas can be efficiently converted into useful chemicals without passing through costly and energy-demanding concentration, compression, and purification processes. This technology will contribute to the reduction of CO2 emissions causing global warming.
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