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Update(MM/DD/YYYY):03/01/2022

Development of a Method for Synthesizing Urea Derivatives from Low-concentration CO2

– Enabling production of useful chemicals from CO2 in thermal power plant emissions –

 
Researchers) TAKEUCHI Katsuhiko, Researcher, MATSUMOTO Kazuhiro, Senior Researcher, CHOI Jun-Chul, Team Leader, Catalyst Design Team, FUKAYA Norihisa, Team Leader, Heteroatom Chemistry Team, SATO Kazuhiko, Director, Interdisciplinary Research Center for Catalytic Chemistry

Points

  • Development of a technology that can synthesize urea derivatives, which are useful chemicals, from low-concentration CO2 contained in exhaust gases, etc.
  • Enables use of low-concentration CO2 without concentration, compression or purification, by going through ammonium carbamate
  • Expected to contribute to the reduction of CO2 emissions, which are considered to cause global warming

Figure of new research results

Outline of newly developed technology for synthesizing urea derivatives from low-concentration CO2


Background

CO2 emissions from thermal power plants account for about 30 % of Japan's total emissions, and since thermal power plants will continue to be important as a base load power source, measures to reduce their CO2 emissions are an urgent issue. Therefore, research has been promoted on Carbon Capture and Storage (CCS) technology for recovering the low-concentration, low-quality CO2 in thermal power plant exhaust gases and storing it underground, and Carbon Capture and Utilization (CCU) technology for converting it into useful chemicals. However, existing techniques have the issues of low incentives for operators and high costs and energy consumption, and there are major barriers to the active entry of private companies that own thermal power plants.

 

Summary

In collaboration with Tosoh Corporation, researchers in AIST developed a catalytic reaction for producing urea derivatives from low-concentration CO2 equivalent to thermal power plant exhaust gas. Urea derivatives are useful chemicals as raw materials for resins, solvents, and pharmaceuticals. In the NEDO project "NEDO Feasibility Study Program/Uncharted Territory Challenge 2050/Direct Conversion of Low-concentration CO2 Derived from Exhaust Gases into Useful Chemicals," R&D was performed on a synthesis process that directly converts low-concentration CO2 into useful chemicals such as polyurethane raw materials and led to development of this technology. This technology can efficiently synthesize various urea derivatives, such as the useful chemical ethylene urea, by acting a titanium catalyst on ammonium carbamate, which is easily obtained from amines and low-concentration CO2 (volume ratio 15 %) equivalent to the exhaust gas at coal-fired power plants, which are the main type in Japan. In addition, low-concentration CO2 in thermal power plant exhaust gas, which had been difficult to use directly, can be efficiently converted into useful chemicals without passing through costly and energy-demanding concentration, compression, and purification processes. As a result, this technology is expected to contribute to the reduction of CO2 emissions, which are considered to cause global warming.





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