Challenge to develop a silicon-based negative electrode that has a high theoretical capacity and does not degrade
Possessing from several times to more than ten times the theoretical capacity of graphite and offering the advantage of stable supply, silicon-based negative electrodes are considered the strongest candidates to be employed as the negative electrodes in next-generation lithium-ion secondary batteries. Among these, SiO is a promising active material, due to its theoretical capacity of 2007 mAh/g, as compared to 372 mAh/g for graphite. SiO is easily vaporized under conditions of high temperature and reduced pressure. It offers the advantage of allowing nanometer-scale SiO thin films to be formed on substrates via vapor deposition. However, due to its low electrical conductivity, there has previously been no concept of directly using a thin film formed by vapor deposition as an electrode.