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Research Highlights, Developed New High Capacity Lithium-ion Secondary Battery That Does Not Degrade

Electronics and Manufacturing
Developed New High Capacity Lithium-ion Secondary Battery That Does Not Degrade
MAMIYA Mikito, AKIMOTO Junji
Advanced Coating Technology Research Center

Improved capacity to approximately 5 times that of a graphite negative electrode

For the developed negative electrode, a nanometer-scale layered structure of silicon monoxide (SiO) is formed through vapor deposition. The electrode realizes approximately five times the capacity of a graphite electrode (the current mainstream electrode), corresponding almost exactly with the theoretical capacity of silicon monoxide.

Figure: Comparison of the properties between previous electrodes and developed one
Comparison of the properties between previous electrodes and developed one

Challenge to develop a silicon-based negative electrode that has a high theoretical capacity and does not degrade

Possessing from several times to more than ten times the theoretical capacity of graphite and offering the advantage of stable supply, silicon-based negative electrodes are considered the strongest candidates to be employed as the negative electrodes in next-generation lithium-ion secondary batteries. Among these, SiO is a promising active material, due to its theoretical capacity of 2007 mAh/g, as compared to 372 mAh/g for graphite. SiO is easily vaporized under conditions of high temperature and reduced pressure. It offers the advantage of allowing nanometer-scale SiO thin films to be formed on substrates via vapor deposition. However, due to its low electrical conductivity, there has previously been no concept of directly using a thin film formed by vapor deposition as an electrode.

Photo: Background

The key is that the SiO thin film behaves as a nanometer-scale material

For the developed negative electrode for lithium-ion secondary batteries, a nanometer-scale thin SiO film was formed on a conductive substrate using vapor deposition and a conductive additive was then layered on this thin film. The new electrode achieves 2000 mAh/g, approximately five times 372 mAh/g for a graphite negative electrode, corresponding almost exactly to the theoretical capacity of SiO (2007 mAh/g). In addition, the developed electrode maintained its capacity even after more than 500 charge-discharge cycles, clearly demonstrating that it displays long life at high capacity. This can be expected to increase the energy density of negative electrodes, and advance the realization of increased capacity and reduced size in lithium-ion secondary batteries.

Photo: New results

Combine with a positive electrode for practical application

This electrode requires a large capacity in the 1st charging process. If it is used as is, the lithium of the positive electrode will be consumed and the performance will immediately drop. To avoid this problem, the electrode must be pre-doped with lithium before a battery is fabricated by combining a positive electrode and this one. The performance verification is underway with the objective of practical application.

Photo: AKIMOTO Junji, MAMIYA Mikito

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