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Research paper : Establishment of compact processes (A. Suzuki et al.)−160−Synthesiology - English edition Vol.3 No.2 (2010) [11][12][13][14][15][16][17][18][19][20]continuous hydrothermal synthesis of nano-size particles, J. Chem. Eng. Japan, 40 (8), 622-629 (2007).K. Mae, A. Suzuki, T. Maki, Y. Hakuta, H. Sato and K. Arai: A new micromixer with needle adjustment for instant mixing and heating under high pressure and high temperature, J. Chem. Eng. Japan, 40 (12), 1101-1107 (2007).Y. Wakashima, K. Hatakeda, S. –I. Kawasaki and A. Suzuki: Performance evaluation of a high pressure microtube as a high-speed heating device for supercritical state generation, J. Chem. Eng. Japan, 41 (2), 76-83 (2008).M. Sato, N. Otabe, T. Tuji, K. Matsushima, H. Kawanami, M. Chatterjee, T. Yokoyama, Y. Ikushima and T. M. Suzuki: Highly-selective and high-speed Claisen rearrangement induced with subcritical water microreaction in the absence of catalyst, Green Chem., 11, 763-766 (2009).M. Sato, K. Matsushima, H. Kawanami and Y. Ikushima: A highly selective, high-speed, and hydrolysis-free O-acylation in subcritical water in the absence of a catalyst, Angew. Chem., Int. Ed., 46, 6284-6288 (2007).H. Kawanami, K. Matsushima, M. Sato and Y. Ikushima: Rapid and highly selective copper-free Sonogashira coupling in high-pressure, high-temperature water in a microfluidic system, Angew. Chem., Int. Ed., 46, 5129-5132 (2007).AIST Press Release: Anka na to kara seiri kassei busshitsu HMF o jinsoku ni seizo - ko’on ko’atsu maikuro riakuta ni yori jistugen (Quick manufacture of physiologically active substance HMF from low-priced sugar – Realized by high-temperature high-pressure microreactor), April 20, 2009 (in Japanese) http://www.aist.go.jp/aist_j/press_release/pr2009/pr20090420/pr20090420.htmlT. Adschiri, K. Kanazawa and K. Arai: Rapid and continuous hydrothermal crystallization of metal oxide particles in supercritical water, J. Am. Ceram. Soc., 75, 1019-1022 (1992).T. Adschiri, K. Kanazawa and K. Arai: Rapid and continuous hydrothermal synthesis of boehmite particles in subcritical and supercritical water, J. Am. Ceram. Soc., 75, 2615-1618 (1992).C. S. Lee, K. L. Hoy and M. D. Donohue: Supercritical fluid as diluting agent in the liquid mist application of coating (Kotingu no ekitai funmu tofu ni okeru kishakuzai toshiteno chorinkaisei ryutai), Japanese Unexamined Patent Application Publication No. 1989-258770 (Japanese Patent 1927328), application date January 5, 1988 (1988) (in Japanese).A. Suzuki, S. Kawasaki, T. Aizawa, M. Ono, Y. Hayasaka, K. Yukishita, N. Hayasaka, H. Sato, T. Chiyokubo and A. Nakatsuka: Koatsu maikuro kongoki o mochiita nisanka tanso toso gijutsu no kaihatsu (Development of carbon dioxide painting technology using high-pressure micromixer), Toso Kogaku (Journal of the Japan Coating Technology Association), 44 (7), 230-237 (2009) (in Japanese).AuthorsAkira SuzukiCompleted the master’s program at the Department of Chemical Engineering, Graduate School of Engineering, Tokyo Institute of Technology in March 1978. Doctor of Engineering in 1990 (Tokyo Institute of Technology). Joined a water treatment engineering company in April 1978. Engaged in the research and development for supercritical water oxidation process and succeeded in its practical application for the first time in the world. Joined AIST in April 2003. Has been working on R&D mainly for supercritical fluid engineering, and currently aims to establish a new process from the perspective of concert of supercritical technology and micro technology. In this paper, was involved in all aspects, but was particularly in charge of the establishment of high-pressure microengineering and the development of innovative painting device.Hajime KawanamiCompleted the doctorate program at the Department of Chemistry, Graduate School of Science, Tohoku University in March 1997. Doctor (Science). Worked as an assistant at the Faculty of Science and Engineering, Kinki University, and joined AIST in April 2001. Studied the chemistry of carbon dioxide and water under high-pressure and high-temperature conditions from the standpoint of organic synthesis and organic reaction. Won the Minister of Economy, Trade and Industry Award of the 4th Green Sustainable Chemistry Award (2005). In this paper, was in charge of the establishment of the compact process using high-pressure microengineering and the organic synthetic process using high-pressure and high-temperature water.Shin-ichiro KawasakiCompleted the master’s program at the Department of Mechanical Engineering, Graduate School of Science and Engineering, Kagoshima University in March 1996. Joined a water treatment engineering company in April 1996, and engaged in research for the practical application of supercritical water oxidation (SCWO) process for the complete decomposition of persistent hazardous waste (such as polychlorinated biphenyl and dioxin). Completed the doctorate program for Environmental Chemistry and Ecoengineering at the Graduate School of Environmental Studies, Tohoku University in March 2006. Doctor (Environmental Studies). Joined AIST in April 2006, and engages in engineering research for the technology of using supercritical water and supercritical carbon dioxide. Particularly specializes in the development of the micromixer, and studies the metal oxide fine particle synthesis by supercritical hydrothermal process as the core research for fluid mixing devices. In this paper, was in charge of the development of the micromixer and the development of the metal oxide fine particle synthesis using supercritical water.Kiyotaka HatakedaCompleted the doctorate program at the Graduate School of Environmental Studies, Tohoku University in March 2005. Doctor (Environmental Studies). Joined the National Industrial Arts Research Institute in 1966. Worked at the Government Industrial Research Institute, Tohoku, Tohoku National Industrial Research Institute, and then at AIST. Experimentally clarified the synthesis of -caprolactam that initiated the research of organic synthesis using supercritical water. In this paper, was essentially in charge of the continuous synthetic system of the nitro compounds under high-pressure and high-temperature water conditions.

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