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AIST TODAYNo.44 2012-2 [ PDF:7.7MB ]


Development of positive electrode materials for low-cost and high-performance rechargeable lithium-ion batteries
- Co- and Ni-free and high capacity positive electrode materials -

[ PDF:619KB ]

New oxide materials for the positive electrode consisting of lithium, iron, titanium, and manganese (Li1+x(Fe0.3Mn0.7)1-xO2 and Li1+x(Fe0.3Mn05Ti0.2)1-xO2, 0<x<1/3) are developed by a wet chemical method including carbothermal reduction process. These materials do not contain rare metals, cobalt and nickel, and have favorable battery characteristics (about 250 mAh/g of initial discharge capacity and above 80 % of initial cycle efficiency) in the same potential range (2.0-4.8 V) as that of conventional positive electrodes (Li1.2Co0.13Ni0.13Mn0.54O2). This development offers a high prospect for conserving resources and reducing the cost of rechargeable lithium-ion batteries used in electric vehicles by utilizing iron and titanium.

Figure
Comparison of charge and discharge cycle characteristics of two types of newly developed positive electrode material for up to 20 cycles at 30 ℃
Metallic lithium is used as the negative electrode material. (potential range: 2.0 V to 4.8 V)

Relational Information
AIST TODAY Vol.12 No.3 p.12 (2012)


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