New oxide materials for the positive electrode consisting of lithium, iron, titanium, and manganese (Li1+x(Fe0.3Mn0.7)1-xO2 and Li1+x(Fe0.3Mn05Ti0.2)1-xO2, 0<x<1/3) are developed by a wet chemical method including carbothermal reduction process. These materials do not contain rare metals, cobalt and nickel, and have favorable battery characteristics (about 250 mAh/g of initial discharge capacity and above 80 % of initial cycle efficiency) in the same potential range (2.0-4.8 V) as that of conventional positive electrodes (Li1.2Co0.13Ni0.13Mn0.54O2). This development offers a high prospect for conserving resources and reducing the cost of rechargeable lithium-ion batteries used in electric vehicles by utilizing iron and titanium.
|