National Institute of Advanced Industrial Science and Technology (AIST)
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AIST TODAYNo.43 2012-1 [ PDF:5.5MB ]


New recyclable green catalyst
- Efficient catalyst for oxidation reaction using metal-complex-type organic nanotubes -

[ PDF:846KB ]
Masaru AOYAGI
Nanotube Research Center
e-mail address

We have discovered that nickel-complex-type organic nanotubes (Ni-ONTs) function as the catalyst for oxidation reactions of various organic compounds, indispensable for industries, in water at room temperature. Ni-ONTs were synthesized by the mass production method developed by AIST. Ni-ONT can be synthesized by the simple operation of mixing inexpensive an amphiphilic molecule, glycylglycine connected with a fatty acid, and nickel salt in solvents. Because all nickel ions are exposed on the inside and the outside surfaces of the nanotube, Ni-ONT is expected to provide excellent catalytic sites. Since Ni-ONT is solid in water, it can be easily recovered through filtration after catalytic reactions and is also recyclable. Therefore, Ni-ONT is expected to contribute to green innovation.

Figure
Schematic illustration and electron microscope image of Ni-ONT

Relational Information
AIST TODAY Vol.11 No.10 p.18 (2011)


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