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AIST TODAYNo.39 2011-1 [ PDF:9.4MB ]


Single-walled carbon nanotubes as capacitor electrodes operable at 4 V
- Leading the way to development of small, light, and high-performance capacitors -

[ PDF:261KB ]
Kenji HATA
Nanotube Research Center

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We have developed a super capacitor electrode using as-grown single-walled carbon nanotubes (SWCNTs), synthesized by water-assisted chemical vapor deposition. The aligned SWCNT ensembles have better electronic and ionic conductivities compared to activated carbon (AC) due to their cohesion, crystallinity, and absence of filling/binder material. Specifically by fabricating electrodes purely from SWCNTs, with high carbon purity (99.98 %), a higher voltage range of 4 V is achieved compared to only 3 V for AC. Additionally these SWCNT electrodes maintain durability (3.6 % decline over 1000 cycles at 4 V).

Furthermore, due to their high electronic conductivity, the SWCNT electrodes can operate without full coverage by metal current-collectors, thus enabling significant device weight reduction. The performance of a SWCNT device without current-collectors is estimated for an energy density at 17 Wh/kg and for a maximum power density rating at 24 kW/kg.

Figure
SEM image of SWCNT electrode (left) and cell assembly without metal current-collectors (right)

Relational Information
AIST TODAY Vol.10 No.12 p.13 (2010)


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