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AIST TODAYNo.8 Spring 2003


Role of the Atomic Modulations in Aperiodic Composite Crystal

Yoshito GOTOH
Institute for Materials & Chemical Process
e-mail address

Recently, advanced materials with unusual electronic and/or magnetic properties have been desired. Aperiodic crystals with long range ordered atomic arrangements, for example, present interesting structural properties for the functional materials above mentioned. Especially, in the composite crystals with plural substructures, a variety of interesting properties for superconductors or thermoelectric materials have been observed because there are mutual lattice modulations between the substructures. The (3+1)-dimensional superspace group symmetry is the most convenient method to describe the modulated structures of aperiodic crystals. By the use of the superspace group approach, the mechanism of hole transfer in (Sr2Cu2O3)0.70CuO2, "Sr14Cu24O41" has been investigated.

Figure
Modulated composite structure of (Sr2Cu2O3)0.70CuO2, "Sr14Cu24O41".

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AIST Today Vol. 3, No. 3 (2003) 17



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